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Beilstein J. Org. Chem. 2019, 15, 2052–2058, doi:10.3762/bjoc.15.202
Graphical Abstract
Figure 1: Schematic diagram of the S. cerevisiae sesquiterpene overproduction platform and the products of Tv...
Figure 2: Phylogenetic analysis of Tvi09626 with other characterised terpene synthases. Six clades are marked...
Figure 3: GC–MS chromatogram of products in vivo (I), in yeast YZL141 (II), in vitro Tvi09626 with FPP (III),...
Figure 4: Characterisation of Tvi09626 products. (A) Mass spectra of compound 1 at tR = 13.46 min with m/z 22...
Figure 5: GC–MS chromatogram for the metal ion dependency assay.
Beilstein J. Org. Chem. 2016, 12, 2372–2377, doi:10.3762/bjoc.12.231
Scheme 1: Synthesis of N-phosphonyl-β-amino Weinreb amides.
Scheme 2: Aminochlorination of α,β-unsaturated ketones in ionic liquid.
Scheme 3: Conversion of β-amino Weinreb amides to aziridines.
Figure 1: Possible hydrogen bonding conformation.
Scheme 4: Resonance structures of Weinreb amides.
Scheme 5: Transformation of trans-aziridine.
Scheme 6: Proposed mechanism of aminochlorination of α,β-unsaturated Weinreb amides.
Beilstein J. Org. Chem. 2015, 11, 2343–2349, doi:10.3762/bjoc.11.255
Figure 1: Molecular structure of TTF derivatives T1 and T2.
Scheme 1: The synthetic routes of compounds T1 and T2.
Figure 2: SEM images of T1 (a) and T2 (b) films on glass substrates (drop-coated from diluted T1 or T2 soluti...
Figure 3: The UV–vis spectra of T1 (a) and T2 (b) at different concentrations in ethyl acetate.
Figure 4: IR spectra of (a) T1, (b) T2, (c) TCNQ, (d) T2/TCNQ, and (e) T1/TCNQ.
Figure 5: (a) UV–vis spectra of T1 solutions TCNQ and T1/TCNQ in ethyl acetate (1 × 10−3 M). (b) UV–vis spect...
Figure 6: Cyclic voltammograms of T1 and T2 in DCM. Conditions: 0.1 M tetrabutylammonium hexafluorophosphate,...
Figure 7: Cyclic voltammograms of T1 and TCNQ in DCM. Conditions: 0.1 M tetrabutylammonium hexafluorophosphat...